Towards High-Performance Lewis Acid Organocatalysis
Ratjen L., van Gemmeren M., Pesciaioli F., List B.
Research article (journal) | Peer reviewedAbstract
The combination of Lewis acid organocatalysis and internal hydrogen-bond assistance was used to develop a new type of highly active disulfonimide catalyst. The increased Lewis acidity was documented by activity comparisons as well as theoretical investigations. Finally, the potential of the hydrogen-bond-assisted disulfonimide catalyst was demonstrated by its application in an enantioselective transformation. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Details about the publication
Journal: Angewandte Chemie International Edition (Angew. Chem. Int. Ed.)
Volume: 53
Issue: 33
Page range: 8765-8769
Status: Published
Release year: 2014
Language in which the publication is written: English
Link to the full text: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84905748802&origin=inward
Keywords: catalyst design; disulfonimides; Lewis acids; organocatalysis; silylium ions
Authors from the University of Münster
| van Gemmeren, Manuel | Professur für Organische Chemie (Prof. Glorius) |