Towards High-Performance Lewis Acid Organocatalysis
Ratjen L., van Gemmeren M., Pesciaioli F., List B.
Forschungsartikel (Zeitschrift) | Peer reviewedZusammenfassung
The combination of Lewis acid organocatalysis and internal hydrogen-bond assistance was used to develop a new type of highly active disulfonimide catalyst. The increased Lewis acidity was documented by activity comparisons as well as theoretical investigations. Finally, the potential of the hydrogen-bond-assisted disulfonimide catalyst was demonstrated by its application in an enantioselective transformation. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Details zur Publikation
Fachzeitschrift: Angewandte Chemie International Edition (Angew. Chem. Int. Ed.)
Jahrgang / Bandnr. / Volume: 53
Ausgabe / Heftnr. / Issue: 33
Seitenbereich: 8765-8769
Status: Veröffentlicht
Veröffentlichungsjahr: 2014
Sprache, in der die Publikation verfasst ist: Englisch
Link zum Volltext: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84905748802&origin=inward
Stichwörter: catalyst design; disulfonimides; Lewis acids; organocatalysis; silylium ions
Autor*innen der Universität Münster
| van Gemmeren, Manuel | Professur für Organische Chemie (Prof. Glorius) |