Use of natural binders and ionic liquid electrolytes for greener and safer lithium-ion batteries

Kim GT, Jeong SS, Joost M, Rocca E, Winter M, Passerini S, Balducci A

Research article (journal)

Abstract

This manuscript reports on the development of a safe and green lithium-ion battery containing sodium salt of CarboxyMethylCellulose (CMC) as binder lithium tit mate (Li4Ti5O12) as anodic active material lithium iron phosphate (LiFePO4) as cathodic active material and an electrolytic solution based on the ionic liquid N-butyl-N-methylpyrrolidinium bis(fluorosulfonyl)imide (PYR14FSI) The battery showed at room temperature a very stable specific capacity of 140 mAh g(-1) constant for more than 150 cycles This indicated that the introduction of low cost and environmentally benign binders like CMC and nonflammable electrolytes such as PYR14FSI represents a viable strategy for the development of new greener and safer lithium-ion batteries (C) 2010 Elsevier B V All rights reserved

Details about the publication

JournalJournal of Power Sources
Volume196
Issue4
Page range2187-2194
StatusPublished
Release year2011 (15/02/2011)
Language in which the publication is writtenEnglish
DOI10.1016/j.jpowsour.2010.09.080
KeywordsLithium batteries CMC LiFePO4 Li4Ti5O12 Ionic liquid PYR14FSI electrochemical performance composite electrodes polymer electrolyte negative electrode low-cost graphite lifepo4 anodes water stability

Authors from the University of Münster

Balducci, Andrea
Institute of Physical Chemistry
Jeong, Sangsik
Institute of Physical Chemistry
Joost, Mario
Institute of Physical Chemistry
Kim, Guk-Tae
Institute of Physical Chemistry
Passerini, Stefano
Münster Electrochemical Energy Technology Battery Research Center (MEET)
Winter, Martin
Münster Electrochemical Energy Technology Battery Research Center (MEET)