Stereoselective palladium-catalyzed carboaminoxylations of indoles with arylboronic acids and TEMPO.
Kirchberg S, Fröhlich R, Studer A
Research article (journal)Abstract
Indoles are not indolent: Various indoles react with arylboronic acids chemodivergently. C-H arylation of free indole and N-methylindole gives the corresponding C(2)-arylated indoles A whereas N-acylated, N-benzoylated, and N-Boc-protected indoles provide the corresponding arylcarboaminoxylated products B with excellent diastereoselectivity in good to excellent yields.
Details about the publication
Journal: Angewandte Chemie International Edition (Angew. Chem. Int. Ed.)
Volume: 48
Issue: 23
Page range: 4235-8
Status: Published
Release year: 2009 (31/12/2009)
Authors from the University of Münster
| Fröhlich, Roland | Organic Chemistry Institute |
| Kirchberg, Sylvia | Organic Chemistry Institute |
| Studer, Armido | Professur für Organische Chemie (Prof. Studer) |