An Anionic Amido-Substituted Seven-Vertex Siliconoid Cluster.

Keuter, J; Dimitrova, M; Janka, O; Hepp, A; Berger, RJF; Lips F

Research article (journal) | Peer reviewed

Abstract

at room temperature within five weeks. Anion 2 was investigated by natural population analysis and visualization of intrinsic atomic orbitals. Magnetically induced current-density calculations of 2 revealed two distinct strong diatropic vortices that sum up in one direction and create a strongly shielded apical silicon atom in 2.

Details about the publication

JournalChemistry - A European Journal (Chem. Eur. J.)
Volume28
Issue45
Page range1-6
StatusPublished
Release year2022 (10/08/2022)
Language in which the publication is writtenEnglish
DOI10.1002/chem.202201473
Link to the full texthttps://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202201473
Keywordssilanide, NMR, 29Si-NMR

Authors from the University of Münster

Hepp, Alexander
Professorship of Inorganic Chemistry (Prof. Hahn)
Lips, Felicitas
Independent Junior Research Group Dr. Felicitas Lips (AG Lips)