Phosphorescent Pt(ii) complexes bearing a monoanionic C^N^N luminophore and tunable ancillary ligands
Hebenbrock, M.; Stegemann, L.; Kösters, J.; Doltsinis, N. L.; Müller, J.; Strassert, C. A.
Research article (journal) | Peer reviewedAbstract
A versatile design strategy is presented towards new monoanionic pincer luminophores, showing that cyclometallating C^N^N ligands can yield phosphorescent Pt(ii) complexes even if a neutral 1,2,3-triazole ring is inserted by click chemistry. The overall charge, intermolecular interactions and excited state properties can be manipulated and controlled by varying the nature of the ancillary ligand, and its effect on the structural and the triplet state characteristics can be thoroughly investigated and correlated by means of theory and spectroscopy.
Details about the publication
Journal: Dalton Transactions (Dalton Trans.)
Volume: 46
Issue: 10
Page range: 3160-3169
Status: Published
Release year: 2017
Language in which the publication is written: German
DOI: 10.1039/C7DT00393E
Link to the full text: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85014797459&origin=inward
Keywords: monoanionic pincer luminophore
Authors from the University of Münster
| Doltsinis, Nikos | Professur für Festkörpertheorie (Prof. Doltsinis) |
| Hebenbrock, Marian | Professorship of Inorganic Chemistry (Prof. Müller) |
| Müller, Jens | Professorship of Inorganic Chemistry (Prof. Müller) |
| Stegemann, Linda | Interface Physics Group (Prof. Fuchs) |
| Strassert, Cristian | Professoship for Coordination Chemistry and Functional Imaging |