Galvanic Corrosion of Lithium‐Powder‐Based Electrodes

Kolesnikov Aleksei, Kolek Martin, Dohmann Jan Frederik, Horsthemke Fabian, Börner Markus, Bieker Peter, Winter Martin, Stan Marian Cristian

Abstract

Lithium metal is considered to be the most promising anode for the next generation of batteries if the issues related to safety and low coulombic effi- ciency can be overcome. It is known that the initial morphology of the lithium metal anode has a great influence on the cycling characteristics of a lithium metal battery (LMB). Lithium-powder-based electrodes (Li p -electrodes) are reported to diminish the occurrence of high surface area lithium deposits. Usually, ultra-thin lithium foils (<50 µm) and Li p -electrodes are prepared on a copper substrate, thus a metal–metal contact area is generated. The com- bination of these two metals in the presence of an electrolyte, however, can lead to galvanic corrosion. Herein, the corrosion behavior of Li p -electrodes is studied. The porosity of such electrodes leads to a high amount of acces- sible Cu surface in contact with electrolyte. As a consequence, Li p -electrodes aged for 1 week in the electrolyte show spontaneous lithium dissolution near the junction to copper and void formation on the lithium-powder particles. This corrosion process affects the delivered capacity of Li p -electrodes and increases the overvoltage of the lithium electrodissolution process. The occur- rence of corrosion at the Cu|Li p interface raises concerns about the practicality of multi-metallic component systems for LMBs.