Block copolymer-directed synthesis of porous anatase for lithium-ion battery electrodes

McRae OF, Xia Q, Tjaberings S, Gröschel AH, Ling CD, Müllner M

Research article (journal) | Peer reviewed

Abstract

A templating method is developed to produce porous nanocrystalline anatase materials for negative electrodes in lithium-ion batteries (LIBs). Amphiphilic diblock copolymers are used to generate template films with phase-separated internal structure. Subsequent swelling with acidified titanium(IV) bis(ammonium lactato) dihydroxide (TALH) solution yielded structured hybrid films. Upon heating, the formation of TiO2 nanocrystals is induced, resulting in a three-dimensional mesoporous structure directed by the bulk morphology of the polymer template. In comparison to commercial nanosized anatase, the structured anatase shows significant performance improvements in lithium-ion coin cell batteries in terms of capacity, stability, and rate capability. {\textcopyright} 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019, 57, 1890–1896.

Details about the publication

JournalJournal of Polymer Science Part A: Polymer Chemistry
Volume57
Issue18
Page range1890-1896
StatusPublished
Release year2019
Language in which the publication is writtenEnglish
DOI10.1002/pola.29312
Link to the full texthttp://doi.wiley.com/10.1002/pola.29312
KeywordsTiO2; anionic polymerization; hexagonal phase; hybrid materials; polymer bulk

Authors from the University of Münster

Gröschel, Andre
Professorship of Physical chemistry (Prof. Gröschel)
Center for Soft Nanoscience
Tjaberings, Stefanie
Professorship of Physical chemistry (Prof. Gröschel)