Brønsted Acid Catalyzed Asymmetric Silylation of Alcohols
Hyodo K., Gandhi S., van Gemmeren M., List B.
Research article (journal) | Peer reviewedAbstract
Abstract We report a catalytic enantioselective desymmetrization of meso-1,2-diols by monosilylation using a chiral enantiopure Brønsted acid as catalyst and hexamethyldisilazane (HMDS) as silyl source.
Details about the publication
Journal: SYNLETT
Volume: 26
Issue: 8
Page range: 1093-1095
Status: Published
Release year: 2015
Language in which the publication is written: English
Link to the full text: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84938417130&origin=inward
Keywords: asymmetric counteranion-directed catalysis (ACDC); desymmetrization; enantioselective Brønsted acid catalysis; meso-diols; silyl transfer
Authors from the University of Münster
| van Gemmeren, Manuel | Professur für Organische Chemie (Prof. Glorius) |