Synthesis and structure of a coordination polymer based on 6-furylpurine
Sinha I, Kösters J, Müller J
Research article (journal) | Peer reviewedAbstract
The synthesis and structure of [Ag(9-methyl-6-furylpurine)( NO3)]n are reported. The title compound represents a rare example of a purine derivative metalated at all three endocyclic nitrogen atoms. It forms a two-dimensional coordination polymer comprising 14-membered trinuclear metallacycles. Density functional theory calculations helped to understand the metal-binding behavior of the 6-furylpurine moiety by showing the silver(I)-binding affinities of all three nitrogen donor atoms to be essentially identical under aqueous conditions.
Details about the publication
Journal: Zeitschrift für Naturforschung B - A Journal of Chemical Sciences
Volume: 71
Page range: 1051-1055
Status: Published
Release year: 2016 (14/09/2016)
Language in which the publication is written: English
Link to the full text: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84994613416&origin=inward
Keywords: Coordination polymer; Purine; Silver
Authors from the University of Münster
| Müller, Jens | |
| Sinha, Indranil |
Projects the publication originates from
NRW Research School "Molecules and Materials – A Common Design Principle" (Molecules and Materials) Duration: 01/10/2009 - 31/10/2012 Funded by: Federal Ministry of Culture and Science of the Federal State of North Rhine-Westphalia Type of project: Individual project |
Doctorates the publication originates from
| Metal-mediated base pairs of 6-substituted purines Candidate: Sinha, Indranil | Supervisors: Müller, Jens Period of time: 10/10/2011 - 29/07/2015 Doctoral examination procedure finished at: Doctoral examination procedure at University of Münster |