The missing link in the coordination chemistry of hydrazines--a hydrazinetriide [N-N(Me)](3-) anion coordinated to five Al atoms.
Uhl W, Hepp A, Layh M, Rezaeirad B
Research article (journal) | Peer reviewedAbstract
The heptanuclear aluminium-nitrogen cage compound [(AlMe2)4(AlMe)3(NHNMe)3(N-NMe)(OMe)] contains the unique hydrazinetriide fragment [N-N(Me)]3- stabilized by coordination to five Al atoms. It was synthesised by thermolysis of the sesqui-hydrazide Al[(μ-NH-NHMe)2AlMe2]3 in refluxing toluene in the presence of a small quantity of methanol.
Details about the publication
Journal: Chemical communications (Chem. Commun.)
Volume: 48
Issue: 12
Page range: 1799-801
Status: Published
Release year: 2012 (07/02/2012)
Language in which the publication is written: English
DOI: 10.1039/c2cc16208c
Authors from the University of Münster
| Hepp, Alexander | Professorship of Inorganic Chemistry (Prof. Hahn) |
| Layh, Marcus | Professorship of Inorganic Chemistry (Prof. Uhl) |
| Rezaeirad, Babak | Institute of Inorganic and Analytical Chemistry |
| Uhl, Werner | Professorship of Inorganic Chemistry (Prof. Uhl) |