A New Approach towards the Asymmetric Fluorination of Alkenes Using Anionic Phase-Transfer Catalysts.
Hennecke U
Research article (journal)Abstract
Chiral anions can do it: Asymmetric phase-transfer catalysis is no longer limited to cationic catalysts. Lipophilic BINOL phosphate anions are superior catalysts for the asymmetric electrophilic fluorination of alkenes under phase-transfer conditions. Now complex fluorinated compounds can be synthesized selectively from simple alkene starting materials.
Details about the publication
Journal: Angewandte Chemie International Edition (Angew. Chem. Int. Ed.)
Volume: 51
Issue: 19
Page range: 4532-4
Status: Published
Release year: 2012 (07/05/2012)
Language in which the publication is written: Uncoded languages
Authors from the University of Münster
| Hennecke, Ulrich |
Projects the publication originates from
Duration: 01/11/2012 - 31/10/2015 | 1st Funding period Funded by: DFG - Individual Grants Programme Type of project: Individual project |