Enantioselective Haloetherifications Catalyzed by 1,1'-Bi-2-naphthol (BINOL) Phosphates: From Symmetrical Alkenediols to Simple Alkenols.

Müller CH, Rösner C, Hennecke U

Research article (journal) | Peer reviewed

Abstract

Asymmetric haloetherifications can be conducted using 1,1'-bi-2-naphthol (BINOL) phosphates as catalyst. In combination with simple N-haloamides such as N-iodopyrrolidinone or N-bromosuccinimide, good enantioselectivities can be achieved. However, depending on the substrate, the choice of BINOL phosphate is important, and different catalysts show remarkably different selectivities.

Details about the publication

JournalChemistry - An Asian Journal
Volume11
StatusPublished
Release year2014 (19/05/2014)
Language in which the publication is writtenEnglish
DOI10.1002/asia.201402229

Authors from the University of Münster

Hennecke, Ulrich
Professur für Organische Chemie (Prof. Studer)