Unprecedented dinuclear silver(i)-mediated base pair involving the DNA lesion 1,N6-ethenoadenine
Mandal S, Hepp A, Müller, J
Research article (journal) | Peer reviewedAbstract
© The Royal Society of Chemistry 2015. The DNA lesion 1,N6-ethenoadenine (εA) has been investigated with respect to its metal-binding properties. A synthetic DNA duplex comprising an εA:εA mispair readily forms doubly silver(i)-mediated base pairs εA-Ag(i)2-εA, representing the first example for a dinuclear metal-mediated homo base pair of a purine derivative. It also constitutes the first example for a Hoogsteen-type metal-mediated homo base pair within a B-DNA duplex. This journal is
Details about the publication
Journal: Dalton Transactions (Dalton Trans.)
Volume: 44
Page range: 3543null
Status: Published
Release year: 2015 (28/11/2014)
Language in which the publication is written: English
DOI: 10.1039/C4DT02663B
Authors from the University of Münster
| Hepp, Alexander | Professorship of Inorganic Chemistry (Prof. Hahn) |
| Mandal, Soham | Professorship of Inorganic Chemistry (Prof. Müller) |
| Müller, Jens | Professorship of Inorganic Chemistry (Prof. Müller) |
Promotionen, aus denen die Publikation resultiert
| Metal-Mediated Base Pairs with Ethenoadenine, a Versatile Nucleobase Surrogate Candidate: Mandal, Soham | Supervisors: Müller, Jens Period of time: 08/10/2012 - 16/08/2016 Doctoral examination procedure finished at: Doctoral examination procedure at University of Münster |