Ab initio studies of adatom- and vacancy-induced band bending in Bi2Se3

Förster T, Krüger P, Rohlfing M

Research article (journal) | Peer reviewed

Abstract

We investigate the influence of potassium adsorption and selenium vacancies in the surface layer on the electronic properties of the prototypical topological insulator Bi2Se3. These modifications of the surface give rise to oscillations in the charge density that extend deep into the crystal. They result in a long-ranged potential perpendicular to the surface (also referred to as band bending) and new states in the band structure that are reminiscent of the states of a two-dimensional electron gas. Very similar effects have been observed in several experiments. The reorganization of the charge deep inside the crystal as a reaction to the surface modification constitutes a remarkable property of Bi2Se3 and is closely related to its layered structure. The emergence of the long-ranged potential as a direct consequence of the charge reorganization turns out to be a generic property of \BiSe. However, calculations without spin-orbit coupling show that the band bending is not related to the nontrivial topological character of Bi2Se3.

Details about the publication

JournalPhysical Review B - Condensed Matter
Volume91
Issue3
StatusPublished
Release year2015 (30/01/2015)
Language in which the publication is writtenEnglish
DOI10.1103/PhysRevB.91.035313
Link to the full texthttp://link.aps.org/doi/10.1103/PhysRevB.91.035313

Authors from the University of Münster

Förster, Tobias
Institute of Solid State Theory
Krüger, Peter
Professur für Festkörpertheorie (Prof. Rohlfing)
Rohlfing, Michael
Professur für Festkörpertheorie (Prof. Rohlfing)