Synthesis and Application of a Chiral Diborate
Loewer Y, Weiss C, Biju AT, Frohlich R, Glorius F
Research article (journal)Abstract
A chiral diborate with different counterions is reported whose structure was unambiguously confirmed by X-ray analysis. This chiral dianion was used in the resolution of trans-1,2-diamines and also as a chiral shift reagent for NMR analysis of triphenylphosphonium salts.
Details about the publication
Journal: Journal of Organic Chemistry (J. Org. Chem.)
Volume: 76
Issue: 7
Page range: 2324-2327
Status: Published
Release year: 2011 (01/04/2011)
Language in which the publication is written: English
DOI: 10.1021/jo102559s
Keywords: transition-metal catalysis shift-reagent diels-alder counterion strategy trisphat anions boric-acid resolution counteranion complexes ion
Authors from the University of Münster
| Fröhlich, Roland | Organic Chemistry Institute |
| Glorius, Frank | Professur für Organische Chemie (Prof. Glorius) |