A novel halogenochalcogeno(IV)acid: [H3O(dibromo-benzo-15-krone-5)](2)[SeBr6]
Hammerschmidt A, Beckmann I, Lage M, Krebs B
Research article (journal)Abstract
Systematic studies on halogenochalcogeno(IV)acids containing tellurium and bromine led to the new crystalline phase [H3O(Dibromo-benzo-15-Krone-5)](2)[SeBr6] (1). The crystal structure consists of octahedral [SeBr6](2-) anions and oxonium cations stabilized by crownether. 1 crystallizes in the monoclinic space group I 2/m (no. 12) with a = 12.610(3) Angstrom, b 14.101(3) Angstrom, c 13.249(3) Angstrom, beta = 111.76(3)degrees and Z = 2.
Details about the publication
Journal: ZAAC - Zeitschrift für Anorganische und Allgemeine Chemie / Journal of Inorganic and General Chemistry
Volume: 631
Issue: 2-3
Page range: 393-396
Status: Published
Release year: 2005 (31/12/2005)
Language in which the publication is written: English
Keywords: crystal structure halogenochalcogenates(IV) hexabromoselenate(IV) hydronium ion h3o crystal-structures neutron-diffraction
Authors from the University of Münster
| Hammerschmidt, Adrienne |