Radical Amination with Trimethylstannylated Benzophenone Imine
Lamas MC, Vaillard SE, Wibbeling B, Studer A
Research article (journal)Abstract
Intermolecular radical amination reactions of various primary, secondary, and tertiary alkyl radicals by using trimethylstannylated benzophenone imine A as a novel radical acceptor to provide imines of type B are described. These Imines are readily reduced with NaBH4 to the corresponding secondary amines C. The novel radical amination can be combined with typical radical cyclization reactions.
Details about the publication
Journal: Organic letters (Org Lett)
Volume: 12
Issue: 9
Page range: 2072-2075
Status: Published
Release year: 2010 (07/05/2010)
Language in which the publication is written: English
DOI: 10.1021/ol1005455
Keywords: c-n bonds nonactivated olefins acyl radicals reductive carbodiazenylation sulfonyl azides nitrogen bonds alkyl radicals rate constants azo group cyclization
Authors from the University of Münster
| Lamas, Marie-Céline | Organic Chemistry Institute |
| Studer, Armido | Professur für Organische Chemie (Prof. Studer) |