Dynamic Microcrystal Assembly by Nitroxide Exchange Reactions
Schulte B, Tsotsalas M, Becker M, Studer A, De Cola L
Research article (journal) | Peer reviewedAbstract
Sticking together: The pore entrances of dye-loaded green or red zeolite L crystals can be site-specifically modified with either alkoxyamines or nitroxide radicals. Mild radical nitroxide exchange reactions of alkoxyamine-terminated "green" zeolite crystals with nitroxide-terminated "red" crystals leads to highly regular crystal chains that contain up to 15 covalently connected crystals with strictly alternating colors.
Details about the publication
Journal: Angewandte Chemie International Edition (Angew. Chem. Int. Ed.)
Volume: 49
Issue: 38
Page range: 6881-6884
Status: Published
Release year: 2010 (31/12/2010)
Language in which the publication is written: English
Keywords: microcrystals; nitroxide exchange reactions; radicals; self-assembly; zeolite L; free-radical exchange polymer brushes chemistry polymerizations nanocrystals crossover crystals size nanoparticles nanomaterials
Authors from the University of Münster
| Becker, Maike | Organic Chemistry Institute |
| De Cola, Luisa | Nano-Photonics Group (Prof. de Cola) |
| Studer, Armido | Professur für Organische Chemie (Prof. Studer) |