Structural and 121Sb Mössbauer spectroscopic investigations of the antimonide oxides REMnSbO (RE = La, Ce, Pr, Nd, Sm, Gd, Tb) and REZnSbO (RE = La, Ce, Pr)

Schellenberg I, Nilges T, Pöttgen R

Abstract

Quaternary antimonide oxides REMnSbO (RE = La, Cc, Pr, Nd, Sm, Gd, Tb) and REZnSbO (RE = La, Cc, Pr) were synthesized from the RESb monoantimonides and MnO, respectively ZnO, in sealed tubes at 1170 K. Single crystals were obtained from NaCl/KCl salt fluxes. The ZrCuSiAs-type (space Group P4/nmm) structures of LaMnSbO (a = 423.95(7), c = 955.5(27) pm, wR2 = 0.067, 247 F-2), CeMnSbO (a = 420.8(1), c = 950.7(1) pm, wR2 = 0.097, 250 F-2), SmMnSbO (a = 413.1(1), c = 942.3(1) pm, wR2 = 0.068, 330 F-2), LaZnSbO (a = 422.67(6), c = 953.8(2) pm, wR2 = 0.052, 259 F-2), and NdZnSbO (a = 415.9(1), c = 945.4(4) pm, wR2 = 0.109, 206 F-2) were refined from single crystal X-ray diffractometer data. The structures consist of covalently bonded (RE3+O2-)(+) and (T2+Sb3-)(-) layers with weak ionic interlayer interactions. The oxygen and transition metal atoms both have tetrahedral coordination within the layers. Sb-121 Mossbauer spectra of the REMnSbO and REZnSbO compounds show single antimony sites with isomer shifts close to -8 mm s(-1), in agreement with the antimonide character of these compounds. PrMnSbO and NdMnSbO show transferred hyperfine fields of 8 T at 4.2 K.