Pushing the limit of triplet-triplet annihilation photon upconversion towards the UVC range

Zaehringer, Till J. B.; Heusel, Corinna; Schmitz, Matthias; Glorius, Frank; Kerzig, Christoph

Research article (journal) | Peer reviewed

Abstract

Triplet–triplet annihilation photon upconversion (TTA-UC) provides a milder alternative to traditional UVB/UVC photochemistry. However, suitable sensitizer-annihilator pairs are scarce, in particular in the high-energy UV regime. Herein, we present a benzene-based annihilator that, paired with a suitable sensitizer, generates upconverted emission approaching the UVC region for the first time.

Details about the publication

JournalChemical communications (Chem. Commun.)
Volume61
Issue50
Page range9051-9054
StatusPublished
Release year2025 (22/05/2025)
DOI10.1039/d5cc01834j
Link to the full texthttps://pubs.rsc.org/en/content/articlelanding/2025/cc/d5cc01834j
Keywordsphotochemistry; triplet–triplet annihilation; photon upconversion

Authors from the University of Münster

Glorius, Frank
Professur für Organische Chemie (Prof. Glorius)
Heusel, Corinna
Professur für Organische Chemie (Prof. Glorius)