Photo-responsive azobenzene-triazole systems will be designed to allow Z-selective anion binding, resulting in photo-reversible switchable anion availability and catalytic activity. Peptide functionali-zation will enable supramolecular aggregates, with anion binding constants depending on the available space for isomerization and thus on the aggregation state. As a route towards adaptive materials we envision to implement memory by modifying aggregate structures based on the steric requirement of the azotriazole E and Z forms during repeated photoisomerization cycles. The ultimate goal is to construct materials with memory-controlled photo-responsive anion binding properties.
| Garcia Mancheno, Olga | |
| Schönhoff, Monika |
| Garcia Mancheno, Olga | |
| Schönhoff, Monika |
Duration: 01/01/2025 - 31/12/2028 | 2nd Funding period Funded by: DFG - Collaborative Research Centre Type of project: Subproject in DFG-joint project hosted at University of Münster |
Duration: 01/01/2021 - 31/12/2024 | 1st Funding period Funded by: DFG - Collaborative Research Centre Type of project: Main DFG-project hosted at University of Münster |