Synthesis of N-Heterocyclic Carbene Complexes by Oxidative Addition of 4-Iodo-imidazolium Salts Followed by an Unusual Rearrangement

Parusel P. Peter , Dutschke D. Patrick , Hebenbrock Marian , Hepp Alexander , Morris H. Robert , Hahn Ekkehardt F. (2024)

In: ACS Omega, 8(50), 48515-48521. doi:10.1021/acs.organomet.3c00479

Research article (journal) | Peer reviewed | Published

Antiprotozoal Pt(II) Complexes as Luminophores Bearing Monodentate P/As/Sb-Based Donors: An X-ray Diffractometric, Photoluminescence, and 121Sb-Mössbauer Spectroscopic Study with TD-DFT-Guided Interpretation and Predictive Extrapolation toward Bi

Buss, S.; Ketter, L.; Brünink, D.; Schwab, D.; Klenner, S.; Hepp, A.; Kösters, J.; Schmidt, T.J.; Pöttgen, R.; Doltsinis, N.; Strassert, C. (2024)

In: Inorganic Chemistry, 63(22), 10114-10126. doi:10.1021/acs.inorgchem.3c02727

Research article (journal) | Peer reviewed | Published

Synthesis of CAAC Complexes by Oxidative Addition of 2-Chloro-3,3-dimethyl-N-ethylindoleninium Cations to Carbonylmetalates and Subsequent Transmetalation

Hepp, A; Hahn, F.E. (2023)

In: Organometallics, 42(6), 473-478. doi:10.1021/acs.organomet.3c00043

Research article (journal) | Peer reviewed | Published

Room-Temperature Phosphorescence from Pd(II) and Pt(II) Complexes as Supramolecular Luminophores: The Role of Self-Assembly, Metal-Metal Interactions, Spin-Orbit Coupling, and Ligand-Field Splitting.

Theiss T; Buss S; Maisuls I; López-Arteaga R; Brünink D; Kösters J; Hepp A; Doltsinis NL; Weiss EA; Strassert CA (2023)

In: Journal of the American Chemical Society, 145(7), 3937-3951. doi:10.1021/jacs.2c09775

Research article (journal) | Peer reviewed | Published

Formation of CNHC∧Calkyl and CNHC∧Caryl κ2-Chelate Complexes through Competitive sp3- and sp2-CH Activations: An Experimental and Computational Study

Böhme, M.D.; Termühlen, S.; Dutschke, P.D.; Hepp, A.; Hahn, F.E. (2023)

In: ACS Omega, 8(50), 48515-48521. doi:10.1021/acsomega.3c08427

Research article (journal) | Peer reviewed | Published

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Synthesis of N-Heterocyclic Carbene Complexes by Oxidative Addition of 4-Iodo-imidazolium Salts Followed by an Unusual Rearrangement Parusel P. Peter , Dutschke D. Patrick , Hebenbrock Marian , Hepp Alexander , Morris H. Robert , Hahn Ekkehardt F. (2024) In: ACS Omega, 8(50), 48515-48521. doi:10.1021/acs.organomet.3c00479 Research article (journal) \| Peer reviewed \| Published
Adaptive photoluminescence through a bioinspired antioxidative mechanism Rex, T.; Baumert, S.; Hepp, A.; Fernandez, G.; Strassert, C. A. (2024) In: Chemical science, 2024. doi:10.1039/d4sc06096b Research article (journal) \| Peer reviewed \| Published
Antiprotozoal Pt(II) Complexes as Luminophores Bearing Monodentate P/As/Sb-Based Donors: An X-ray Diffractometric, Photoluminescence, and 121Sb-Mössbauer Spectroscopic Study with TD-DFT-Guided Interpretation and Predictive Extrapolation toward Bi Buss, S.; Ketter, L.; Brünink, D.; Schwab, D.; Klenner, S.; Hepp, A.; Kösters, J.; Schmidt, T.J.; Pöttgen, R.; Doltsinis, N.; Strassert, C. (2024) In: Inorganic Chemistry, 63(22), 10114-10126. doi:10.1021/acs.inorgchem.3c02727 Research article (journal) \| Peer reviewed \| Published
Oxidative addition of 8-bromo-9-ethyl-1,N6-ethenoadenine to d10 metals Jahnke, MC; Mandal, S; Kampert, F; Tan, TTY; Müller, J; Hahn, FE (2023) In: Inorganica Chimica Acta, 546, 121291. doi:10.1016/j.ica.2022.121291 Research article (journal) \| Peer reviewed \| Published
Synthesis of CAAC Complexes by Oxidative Addition of 2-Chloro-3,3-dimethyl-N-ethylindoleninium Cations to Carbonylmetalates and Subsequent Transmetalation Hepp, A; Hahn, F.E. (2023) In: Organometallics, 42(6), 473-478. doi:10.1021/acs.organomet.3c00043 Research article (journal) \| Peer reviewed \| Published
Organometallic Borromean Rings and [2]Catenanes Featuring Di-NHC Ligands. Lu, Y; Dutschke, PD; Kinas, J; Hepp, A; Jin, GX; Hahn FE (2023) In: Angewandte Chemie International Edition, 62(11), 1-7. doi:10.1002/anie.202217681 Research article (journal) \| Peer reviewed \| Published
Room-Temperature Phosphorescence from Pd(II) and Pt(II) Complexes as Supramolecular Luminophores: The Role of Self-Assembly, Metal-Metal Interactions, Spin-Orbit Coupling, and Ligand-Field Splitting. Theiss T; Buss S; Maisuls I; López-Arteaga R; Brünink D; Kösters J; Hepp A; Doltsinis NL; Weiss EA; Strassert CA (2023) In: Journal of the American Chemical Society, 145(7), 3937-3951. doi:10.1021/jacs.2c09775 Research article (journal) \| Peer reviewed \| Published
The Effect of Monodentate Co-Ligands on the Properties of Pt(II) Complexes Bearing a Tridentate C^N*N-Luminophore Buss, S.; Geerkens, L.; Cappellari ,M. V.; Hepp, A.; Kösters, J.; Strassert, C.A. (2023) In: Molecules, 28(23). doi:10.3390/molecules28237834 Research article (journal) \| Peer reviewed \| Published
Formation of CNHC∧Calkyl and CNHC∧Caryl κ2-Chelate Complexes through Competitive sp3- and sp2-CH Activations: An Experimental and Computational Study Böhme, M.D.; Termühlen, S.; Dutschke, P.D.; Hepp, A.; Hahn, F.E. (2023) In: ACS Omega, 8(50), 48515-48521. doi:10.1021/acsomega.3c08427 Research article (journal) \| Peer reviewed \| Published
Synthesis and functionalization of the six-vertex anionic amido-substituted silicon cluster [Si6{N(SiMe3)Ph}5]− Helmer, J.; Hepp, A.; Berger, R.J.F.; Lips, F. (2023) In: Dalton Transactions, 52(41), 14949-14955. doi:10.1039/d2dt03952d Research article (journal) \| Peer reviewed \| Published